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Substitution Reactions

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11: Free Radical Substitution and Addition Reactions

people.chem.ucsb.edu

Free radical halogenation reactions of alkanes and cycloalkanes are substitution reactions in which a C-H is converted to a C-X. R3C-H + X2 → R3C-X + H-X While any of the molecular halogens F2, Cl2, Br2, and I2 will halogenate alkanes and cycloalkanes, Br2 or Cl2 are used most often. We will use bromination (X = Br) to illustrate alkane ...

  Reactions, Substitution, Substitution reactions

Experiment 7 — Nucleophilic Substitution

www.amherst.edu

ethanol for SN1 reactions. Briefly explain why (a) the SN1 reaction pathway is disfavored with NaI/acetone, and (b) why the SN2 pathway is disfavored with AgNO3/EtOH. Nucleophilic substitution is one of the most useful and well studied class of organic reactions. These reactions can occur by a range of mechanisms. SN2 and SN1 are the extremes.

  Reactions, Substitution

ORGANIC CHEMISTRY I – PRACTICE EXERCISE Sn1 and Sn2 …

personal.utdallas.edu

8) Would 2-chloropropane or 1-chloro-2,2-dimethylpropane undergo substitution faster with Na+ -CCH? Give the structure of the substitution product. 9) t-butyl chloride undergoes solvolysis in 70% water/30% acetone at a rate slower than in 80% water/20% acetone. Explain.

  Substitution

Organic Chemistry 32-235 Practice Questions for Exam #2 ONE

www.uwosh.edu

which is, in this case, related to whether alkyl groups (substitution pattern) behave as electron withdrawing or donating groups. The answer is (A) 12. Bromination of alkanes is a much slower reaction than chlorination. Which of the following is expected to be the major organic product when 2-methylbutane is allowed to react with Br2 in the

  Substitution

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