Chapter 9: Phase Diagrams
Chapter 9 -1ISSUES TO When we combine two equilibrium state do we get? In particular, if we composition ( , wt% Cu - wt% Ni), and--a temperature (T) many phases do we get?What is the composition of each Phase ?How much of each Phase do we get? Chapter 9: Phase DiagramsPhase BPhase ANickel atomCopper atomChapter 9 -2Phase Equilibria: Solubility LimitIntroduction Solutions solid solutions, single Phase Mixtures more than one Phase Solubility Limit:Max concentration forwhich only a single Phase solution :What is thesolubility limit at 20 C?Answer: 65 wt% Co< 65 wt% sugar:syrupIf Co> 65 wt% sugar:syrup + Phase DiagramPure SugarTemperature ( C)020406080100Co=Composition (wt% sugar)L(liquid solution , syrup)Solubility LimitL(liquid) + S(solid sugar)20406080100Pure WaterAdapted from Fig.
Cu FCC 1.8 0.1278 Ni FCC 1.9 0.1246 Crystal electroneg r (nm) Structure • Both have the same crystal structure (FCC) and have similar electronegativities and atomic radii ( W. Hume – Rothery rules ) suggesting high mutual solubility. Simple solution system (e.g., Ni-Cu solution) • Ni and Cu are totally miscible in all proportions.
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