pH AND SOLUBILITY - scienceattech.com
202This salt 's SOLUBILITY is pH dependent. How?* In a BASIC solution, the concentration of hydroxide ion in solution is high., so SOLUBILITY is LOWER than in pure water.* In an ACIDIC solution, we have a significant amount of hydronium, whichcan react with hydroxide. This lowers the hydroxide concentration and makesmagnesium hydroxide MORE SOLUBLEGeneralizingIf a compound is BASIC, then it will be LESS SOLUBLE in basic solutions, and MORE SOLUBLEin acidic solutions!If a compound is ACIDIC, then it will be MORE SOLUBLE in basic solutions, and LESS SOLUBLEin acidic solutions!If a compound is NEUTRAL (neither acidic nor basic), then its SOLUBILITY will be UNAFFECTED by pHpH AND SOLUBILITY203COMPLEX IONS- are ions that result from the reaction of a Lewis base (like water, ammonia, hydroxide ion, etc.) with a metal ion- The Lewis base attaches to the metal ion by forming a COORDINATE COVALENT BONDwith the metal The product of the reaction is called a "COMPLEX", and the attached Lewis bases are called "LIGANDS"204COMPLEX ION EQUILIBRIUM- Described by the FORMATION CONSTANT, KfWhat does this value for the equilibrium constant say aboutthe favorability of the formation of the complex ion?
pH AND SOLUBILITY. 203 COMPLEX IONS - are ions that result from the reaction of a Lewis base (like water, ammonia, hydroxide ion, ... will greatly INCREASE the solubility of that salt! COMPLEX IONS AND SOLUBILITY. 208 Calculate the solubility (in ppm) of silver chloride in 0.10 M ammonia solution.
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