Transcription of 1.17 Some important structure types a) Rock salt …
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1.17 Some important structure types a) Rock salt …
1(The text is taken from: Basic Solid State Chemistry, by Anthony R. West) some important structure types a) Rock salt (NaCl), zinc blende or sphalerite (ZnS), fluorite (CaF2), antifluorite (Na2O) These structures are considered together because they all have ccp/fcc anions and differ only in the positions of the cations. In Fig. are shown the anions in a fcc unit cell with all possible O, T+ and T- sites for the cations. The different structures are generated as fol1ows: Rock salt: O occupied; T+ and T- empty Zinc blende: T+ (or T-) occupied; O, T- (or T+) empty Antifluorite: T+, T- occupied; O empty Unit cel1s are shown in Fig.
1 (The text is taken from: Basic Solid State Chemistry, by Anthony R. West) 1.17 Some important structure types a) Rock salt (NaCl), zinc blende or sphalerite (ZnS), fluorite (CaF2), antifluorite (Na2O) These structures are considered together because they all have ccp/fcc anions and differ only in the positions of the cations.
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