Transcription of 1. 金属錯体とは 2. 金属錯体の構造 3. 金属錯体の異性現象 4. …
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1. 金属錯体とは 2. 金属錯体の構造 3. 金属錯体の異性現象 4. …
Coordination Chemistry 1. 1. 2. 3. 4. (Metal Complexes) Coordination Chemistry (Coordination Compounds)Werner (Organometallic Complexes)M Hard AcidSoft AcidHard BaseSoft Base (1893 1913 ) HSAB Coordination ChemistryCoordination ChemistryHSAB IIIIIIIVVVI VII VIII IXXXIXII groupvalenveelectrond3d5d4d6d8d7d9d10d10 s2d10s1s1s2 Coordination Chemistry ScTi V Cr MnFe Co Ni Cu ZnY ZrNbMo TcRuRh Pd Ag Cd(La) HfTa W Re OsIrPt Au Hg ScTi V Cr MnFe Co Ni Cu
3]2-(M = Ti, Zr, Hf, L = P 2C 14H 16) S 2C 2R 2 2-(ジチオレン） R = H, Ph, CF 3 small normarized bite (d/r) 多くのd3, d6錯体（これ以外も多い） Cr(III), Fe(II), Co(III), Rh(III) Ir(III), Pd(IV), Pt(IV) [M(H 2O) 6]2+ (M = Fe, Co, Ni, Cu, Zn) [M(H 2O) 6]3+ (M = Ti, V, Cr, Mn) d4 (Mn(III)), d9 (Cu(II))はJahn-Teler正方 …
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