Transcription of 1. 金属錯体とは 2. 金属錯体の構造 3. 金属錯体の異性現象 4. …
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1. 金属錯体とは 2. 金属錯体の構造 3. 金属錯体の異性現象 4. …
Coordination Chemistry 1. 1. 2. 3. 4. (Metal Complexes) Coordination Chemistry (Coordination Compounds)Werner (Organometallic Complexes)M Hard AcidSoft AcidHard BaseSoft Base (1893 1913 ) HSAB Coordination ChemistryCoordination ChemistryHSAB IIIIIIIVVVI VII VIII IXXXIXII groupvalenveelectrond3d5d4d6d8d7d9d10d10 s2d10s1s1s2 Coordination Chemistry ScTi V Cr MnFe Co Ni Cu ZnY ZrNbMo TcRuRh Pd Ag Cd(La) HfTa W Re OsIrPt Au Hg ScTi V Cr MnFe Co Ni Cu Z
120° 90° 平面四角形 square planar 正四面体 tetrahedral Td 109° 四角錐 square pyramidal C4v 90° 三方両錐 trigonal bipyramidal D3h 120° 90° 正八面体 octahedral 90° Oh 三角柱 trigonal prism D3h Au(I), Ag(I) Cu(I), Hg(II) Cu(0), Pd(0) Pt(0) Pt(II), Pd(II), Ni(II) Ir(I), Rh(I) [VO(H 2 O) 4]2+ [Ni(CN) 5]3-Co(III), Rh(III ...
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