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(1976). A32, 751 Revised Effective Ionic Radii and Systematic …

751 Acta Cryst. (1976). A32, 751 Revised Effective Ionic Radii and Systematic Studies of Interatomie Distances in Halides and Chaleogenides BY R. D. SHANNON Central Research and Development Department, Experimental Station, E. L Du Pont de Nemours and Company, Wilmington, Delaware 19898, (Received 30 October 1975; accepted 9 March 1976) The Effective Ionic Radii of Shannon & Prewitt [Acta Cryst. (1969), B25, 925-945] are Revised to include more unusual oxidation states and coordinations. Revisions are based on new structural data, empirical bond strength-bond length relationships, and plots of (1) Radii vs volume, (2) Radii vs coordination number, and (3) Radii vs oxidation state. Factors which affect Radii additivity are polyhedral distortion, partial occupancy of cation sites, covalence, and metallic character.

Acta Cryst. (1976). A32, 751 Revised Effective Ionic Radii and Systematic Studies of Interatomie Distances in Halides and Chaleogenides BY R. D. SHANNON Central Research and Development Department, Experimental Station, E. L Du Pont de Nemours and Company, Wilmington, Delaware 19898, U.S.A.

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