Transcription of 2017年後期物理化学演習 甲南大学理工学部
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2017年後期物理化学演習 甲南大学理工学部
2017 Wref RTILH2Ag/AgClPtW2H+ + 2e-= H2 Wref RTILH2Ag/AgClPtW AgCl+ e-= Ag +Cl- Wref H2 PtW KCl Ag PtAg KCl Ag AgCl iAg|AgCl AgCl+ e-= Ag + V (vsSHE, 25 C) | Ag|AgCl Cl- ~ Ag | AgCl |3 mol dm-3aq. NaCl Ag | AgCl | mol dm-3aq. KCl vs :versus SHE : standard hydrogen electrode AgCl+ e-= Ag +Cl- 2 Cl- AgCl > 3 mol dm-3 25 C Pauling pm 2015 B KClNaClO4 mol dm-3~ mol dm-3)O.
Nernst 式についての注意(3) 現もちいられている形 （濃度ではなく活量であるべき） “for the single potential difference between an electrode and an electrolyte” G. N. Lewis, Proc. Am. Acad. Arts Sci., 43, 259–293 (1907). “while equation XXIX is universally true, the equation of Nernst is obviously only true when the activity of the ion in the electrolyte is ...
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