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7. 立体化学 Stereochemistry−B. 立体配置 Configuration と立 …

7-1* Enantiomer A Plane of Symmetry A Plane of Symmetry ex.) 2-butanol Chiral Achiral7. stereochemistry B. Configuration Asymmetry Enantiomers **HCHOCH2CH3CH3 HCOHCH3CH3CH2 HCHOCH3CH3 Asymmetric CarbonCOOHCRHH2 NCOOHCRNH2H1) 2) L-** (1) L-: D-: (2) Glutamate R = CH2CH2 COOH [ ]D+62 -62 (3) Carvone CH3 OHCCH3CH3 HCOCH3CH2CH2D-a) Optical Polarized Light Polarized Light Polarizer 1 2 Not transmitted-+c /g mL-1l /dm Plane of Polarization 2 1 Not transmittedPartly transmitted : +: Clockwise -: Counter-clockwise Enantiom

7. 立体化学 Stereochemistry−B. 立体配置 Configuration と立体異性体 Stereoisomers 7.1. 不斉 Asymmetry と鏡像異性体 Enantiomers * ≠ * H C HO CH 2CH 3 CH 3 H C CH OH 3 CH 3CH 2 H C HO CH 3 CH 3 Asymmetric Carbon COOH C R H 2N H COOH C R H NH 2 1) 物理化学的性質(融点、沸点、溶解度など):同じ 2 ...

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