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8.044 Lecture Notes Chapter 6: Statistical Mechanics at ...

Lecture NotesChapter 6: Statistical Mechanics at Fixed Temperature(Canonical Ensemble)Lecturer: Derivation of the Canonical Ensemble .. Monatomic, classical, ideal gas, at fixedT.. Two-level systems, re-revisited .. Classical harmonic oscillators and equipartition of energy .. Quantum harmonic oscillators .. Heat capacity of a diatomic ideal gas .. Paramagnetism .. by adiabatic demagnetization .. The Third Law of Thermodynamics .. 6-42 Reading:Greytak, Notes on the Canonical Ensemble;Baierlein, Chapters 5, 13, Reading for :Greytak, Notes on (Raman Spectroscopy of) Derivation of the Canonical EnsembleIn Chapter 4, we studied the Statistical Mechanics of anisolatedsystem. This meant fixedE,V, some fundamental principles (really, postulates), we developed an algorithm for cal-culating (which turns out not to be so practical, as you ll have you thought aboutthe random 2-state systems on pset 6):1.

In Chapter 4, we studied the statistical mechanics of an isolated system. This meant xed E;V;N. From some fundamental principles (really, postulates), we developed an algorithm for cal-culating (which turns out not to be so practical, as you’ll have seen e.g. if you thought about the random 2-state systems on pset 6): 1.Model the system

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