Transcription of Advanced Inorganic Chemistry (Part 1) Basic Solid State ...
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Advanced InorganicChemistry ( part 1) Basic Solid StateChemistryWS 05/06( )Topics of the complete lectureTopics of the complete lecture Introduction special aspects of the Solid State Structure of solids Basic crystallography Characterization of solids:diffraction techniques, electron microscopy,spectroscopy, thermal analysis Bonding in solids Real structure of crystals, defects Electrical, magnetic and optical properties Synthesis of solids Structure-property relationsResourcesResourcesInternet resources ( german) ~ (pdf-downloads) IUCR-teaching resources (International Union for Crystallography, Advanced level)ResourcesResourcesTextbooks:Shrive r, Atkins, Inorganic Chemistry (3rd ed, 1999) Freeman and Company (Chapter 2, 18 ..)recommendationgermanvery good, but not Basic of basics of Simple close packed structures: Basic structure types (structure of simple salts) More complex Complex Structure ofnanomaterialsOutlineOutline is the Solid State interesting?
2.1 Basics of Structures Trends of the ionic radii • ionic radii increase on going down a group • radii of equal charge ions decrease across a period • ionic radii increase with increasing coordination number (the higher its CN the bigger the ions seems to be !!) • the ionic radius of a given atom decreases with increasing charge (r(Fe2 ...
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