Transcription of Amino Acid-Protecting Groups
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Amino Acid-Protecting Groups
1 Amino Acid-Protecting Groups Albert Isidro-Llobet,1 Mercedes lvarez,1,2,3* Fernando Albericio1,2,4* 1 Institute for Research in Biomedicine, Barcelona Science Park, Baldiri Reixac 10, 08028-Barcelona, Spain. 2 CIBER-BBN, Networking Centre on Bioengineering, Biomaterials and Nanomedicine, Barcelona Science Park, Baldiri Reixac 10, 08028-Barcelona, Spain. 3 Laboratory of Organic Chemistry, Faculty of Pharmacy, University of Barcelona, 08028-Barcelona, Spain. 4 Department of Organic Chemistry, University of Barcelona, Mart i Franqu s 1, 08028-Barcelona, Spain. E-mail: RECEIVED DATE *Authors to whom correspondence should be addressed. Fax: 34 93 403 71 26. E-mail: Create PDF files without this message by purchasing novaPDF printer ( ) 2 Contents 1.
Orthogonal protection schemes are usually milder because selective deprotection is governed by alternative cleavage mechanisms rather than by reaction rates. Since the pioneernig work of Bergmann and Zervas, the development of new protecting groups has been deeply tied to peptide chemistry. Protection
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