Archived Lecture Notes #10 - Phase Equilibria and Phase ...

LN 10 Introduction to Solid State Chemistry Lecture Notes No. 10 Phase Equilibria AND Phase DIAGRAMS * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * Sources for Further Reading: 1. Campbell, , Why Do Chemical Reactions Occur?, Prentice-Hall, Englewood Cliffs, NJ, 1965. (Paperback) 2. Barrow, , Physical Chemistry, McGraw-Hill, New York, 1973. 3. H gg, G., General and Inorganic Chemistry, Wiley, 1969. 4. Henish, H., Roy, R., and Cross, , Phase Transitions, Pergamon, 1973. 5. Reisman, A., Phase Equilibria , Academic Press, 1970. * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * PART A: Phase Equilibria AND Phase DIAGRAMS Phase diagrams are one of the most important sources of information concerning the behavior of elements, compounds and solutions.

Normal melting point Supercritical fluid Critical point Solid Liquid Gas Normal boiling point Triple point (Tt) 6.0 x 10-3 1 217.7 P r e s s u r e (a t m) Temperature (oC) 0 0.0098 100 374.4 Phase Diagram of Water Image by MIT OpenCourseWare. LN–10 The number of degrees of freedom of a system is the number of variables that may be

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