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Basic Principles of Atomic Absorption and Atomic Emission ...

1 Basic Principles of Atomic Absorption and Atomic Emission Spectroscopy 2 Source Wavelength Selector Sample Detector Signal Processor Readout P Flame Atomic Emission Spectrometer 3 Flame Atomic Emission Spectrometer 4 Emission Techniques Type Method of Atomization Radiation Source Arc sample heated in an sample electric arc (4000-5000oC) Spark sample excited in a sample high voltage spark Flame sample solution sample aspirated into a flame (1700 3200 oC) Argon sample heated in an sample plasma argon plasma (4000-6000oC) 5 Flame and Plasma Emission Spectroscopy are based upon those particles that are electronically excited in the medium.

Hollow cathode lamps normally operate at currents of 3-15 mA. • If the applied power is raised to several hundred mA, they exhibit a phenomenon called self-reversal. • This giant pulse of current changes the nature of the analyte absorption line so it will only measure the background absorbance. • A total

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