Transcription of CHAPTER 10: COORDINATION CHEMISTRY II: BONDING
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138 CHAPTER 10 COORDINATION CHEMISTRY II: BONDING Copyright 2014 Pearson Education, Inc. CHAPTER 10: COORDINATION CHEMISTRY II: BONDING a. Tetrahedral d 6, 4 unpaired electrons b. [Co(H2O)6]2+, high spin octahedral d 7, 3 unpaired electrons c. [Cr(H2O)6]3+, octahedral d 3, 3 unpaired electrons d. square planar d 7, 1 unpaired electron e. BM = = nn 2 ; n 4 a. [M(H2O)6]3+ with 1 unpaired electron. d1: M = Ti b. [MBr4] with the maximum number of unpaired electrons (5). M3+ with 5 d electrons: M = Fe c. Diamagnetic [M(CN)6]3 . The strong field cyano ligand favors low spin. M3+ with 6 d electrons: M = Co d. [M(H2O)6]2+ having LFSE = 35 o . Both high spin d4 and d9 have the correct o.
10.8 Co(II) is d 7. In tetrahedral complexes, it is generally high spin and has 3 unpaired electrons; in In tetrahedral complexes, it is generally high spin and has 3 unpaired electrons; in octahedral complexes, it is also typically high spin and also has 3 unpaired electrons; in square
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