Transcription of CHAPTER 10: COORDINATION CHEMISTRY II: BONDING
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CHAPTER 10: COORDINATION CHEMISTRY II: BONDING
138 CHAPTER 10 COORDINATION CHEMISTRY II: BONDING Copyright 2014 Pearson Education, Inc. CHAPTER 10: COORDINATION CHEMISTRY II: BONDING a. Tetrahedral d 6, 4 unpaired electrons b. [Co(H2O)6]2+, high spin octahedral d 7, 3 unpaired electrons c. [Cr(H2O)6]3+, octahedral d 3, 3 unpaired electrons d. square planar d 7, 1 unpaired electron e. BM = = nn 2 ; n 4 a. [M(H2O)6]3+ with 1 unpaired electron. d1: M = Ti b. [MBr4] with the maximum number of unpaired electrons (5). M3+ with 5 d electrons: M = Fe c. Diamagnetic [M(CN)6]3 . The strong field cyano ligand favors low spin.
transformation matrix for rotation is provided in Figure 4.16. Application is of this matrix is necessary to deduce the characters involving rotations. 10.12 The e column gives d orbital energies for complexes involving donor ligands only; the Total column gives energies for complexes of ligands that act as both donors and acceptors:
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