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Chapter 15. Statistical Thermodynamics

Boltzmann Distribution Partition Functions Molecular Energies The Canonical Ensemble Internal energy and entropy Derived functionsChapter 15. Statistical ThermodynamicsMajor ConceptsReviewDiscrete Energy levelsParticle in a boxRigid rotorHarmonic OscillatorMathProbability Lagrange MultipliersProperties of lnMicroscopic PropertiesQuantum MechanicsSpectroscopyVibrational frequenciesBond dissociationsMacroscopic PropertiesThermodynamicsHeat capacityCoefficient of expansionStatistical MechanicsStatistical ThermodynamicsStatistical Thermodynamics provides the link between the microscopic ( , molecular) properties of matter and its macroscopic ( , bulk) properties .

Statistical Thermodynamics Statistical thermodynamics provides the link between the microscopic (i.e., molecular) properties of matter and its macroscopic (i.e., bulk) properties. It provides a means of calculating thermodynamic properties from the statistical relationship between temperature and energy.

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