Transcription of CHAPTER 19 TRANSITION METALS AND COORDINATION …
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730 CHAPTER 19 TRANSITION METALS AND COORDINATION chemistry TRANSITION METALS 6. TRANSITION metal ions lose the s electrons before the d electrons. a. Ti: [Ar]4s23d2 b. Re: [Xe]6s24f145d5 c. Ir: [Xe]6s24f145d7 Ti2+: [Ar]3d2 Re2+: [Xe]4f145d5 Ir2+: [Xe]4f145d7 Ti4+: [Ar] or [Ne]3s23p6 Re3+: [Xe]4f145d4 Ir3+: [Xe]4f145d6 7. Cr and Cu are exceptions to the normal filling order of electrons.
734 CHAPTER 19 TRANSITION METALS AND COORDINATION CHEMISTRY NH 3 NH 28. CN− is a weak base, so OH− ions are present. When the acid H 2S is added, OH − and CN− ions are removed as H2O and HCN.The hydrated Ni 2+ complex ion forms after the OH− and CN− ions are removed by addition of H2S.The two reactions are:
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