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CHAPTER 4:The Material Balance for Chemical Reactors

CHAPTER 4:The Material Balance for Chemical ReactorsCopyright 2022 by Nob Hill Publishing, LLCRjVQ1cj1Q0cj0 Conservation of mass rate ofaccumulationof componentj ={rate of inflowof componentj} {rate of outflowof componentj}+ rate of generationof componentjbychemical reactions ( )1 / 152 General Mole BalanceRjVQ1cj1Q0cj0 Conservation of massddt VcjdV=Q0cj0 Q1cj1+ VRjdV( )2 / 152 General Mole Balanceddt VcjdV=Q0cj0 Q1cj1+ VRjdVEquation applies to every Chemical component in the system,j= 1,2,..,ns,including inerts, which do not take place in any componentjenters and leaves the volume element only by convectionwith the inflow and outflow streams, neglecting diffusional flux through theboundary of the volume element due to a concentration diffusional flux will be considered during the development of the materialbalance for the packed-bed / 152 Rate expressionsTo solve the reactor Material Balance , we require an expression for the productionrates,RjRj= i ijriTherefore we requirerias a function ofcjThis is the subject of Chemical kinetics, CHAPTER 5 Here we use common reaction-rate expressions without derivation4 / 152 The Batch ReactorRjThe batch reactor is assum

balance for the packed-bed reactor. 3/152 Rate expressions To solve the reactor material balance, we require an expression for the production rates, R j R j = X i ijri Therefore we require ri as a function of c j This is the subject of chemical kinetics, Chapter 5 Here we use common reaction-rate expressions without derivation 4/152

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