Transcription of CHAPTER 4:The Material Balance for Chemical Reactors
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CHAPTER 4:The Material Balance for Chemical ReactorsCopyright 2022 by Nob Hill Publishing, LLCRjVQ1cj1Q0cj0 Conservation of mass rate ofaccumulationof componentj ={rate of inflowof componentj} {rate of outflowof componentj}+ rate of generationof componentjbychemical reactions ( )1 / 152 General Mole BalanceRjVQ1cj1Q0cj0 Conservation of massddt VcjdV=Q0cj0 Q1cj1+ VRjdV( )2 / 152 General Mole Balanceddt VcjdV=Q0cj0 Q1cj1+ VRjdVEquation applies to every Chemical component in the system,j= 1,2,..,ns,including inerts, which do not take place in any componentjenters and leaves the volume element only by convectionwith the inflow and outflow streams, neglecting diffusional flux through theboundary of the volume element due to a concentration diffusional flux will be considered during the development of t
If the reactor volume is constant (liquid-phase reactions) dc j dt = R j (4.6) Use Equation 4.5 rather than Equation 4.6 if the reactor volume changes signi cantly during the course of the reaction. 7/152 Analytical Solutions for Simple Rate Laws In general the material balance must be solved numerically.
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