Transcription of Chapter 4 The Statistical Physics of non-Isolated systems ...
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Chapter 4. The Statistical Physics of non-Isolated systems : The Canonical Ensemble The boltzmann distribution The independent-particle approximation: one-body parti- tion function Examples of partition function calculations energy , entropy, Helmholtz free energy and the partition function * energy fluctuations Example: The ideal spin-1/2 paramagnet * Adiabatic demagnetization and the 3rd law of thermody- namics Example: The classical ideal gas Vibrational and rotational energy of diatomic molecules * Translational energy of diatomic molecules: quantum treat- ment The equipartition theorem * The Maxwell- boltzmann velocity distribution * What is next? 1. 4 The Statistical Physics of non-Isolated systems : The Canonical Ensemble In principle the tools of Chap.
4.1 The Boltzmann distribution 4.2 The independent-particle approximation: one-body parti-tion function 4.3 Examples of partition function calculations 4.4 Energy, entropy, Helmholtz free energy and the partition function 4.5* Energy fluctuations 4.6 Example: The ideal spin-1/2 paramagnet 4.7* Adiabatic demagnetization and the 3rd law of ...
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