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CHAPTER 5: ANSWERS TO ASSIGNED PROBLEMS Hauser- …

1 CHAPTER 5: ANSWERS TO ASSIGNED PROBLEMS Hauser- General Chemistry I revised 10/14/08 CAUTION: Many different units are used in thermochemistry. Report the units! Also report the sign when appropriate! Consider the following reaction: 2 Mg (s) + O2 (g) 2 MgO (s) H = -1204 kJ (a) Is this reaction exothermic or endothermic? EXOTHERMIC (negative H) (b) Calculate the amount of heat transferred when g of Mg (s) reacts at constant pressure. g Mg ( 1 mol Mg / g) ( -1204 kJ / 2 mol Mg) = -59 kJ (2 SF) COEFFICIENTS MATTER! Note the 2 for Mg. When solutions containing silver ions and chloride ions are mixed, silver chloride precipitates: Ag+ (aq) + Cl- (aq) AgCl (s) H = kJ (a) Calculate H for production of mol of AgCl by this reaction.

CHAPTER 5: ANSWERS TO ASSIGNED PROBLEMS Hauser- General Chemistry I revised 10/14/08 CAUTION: Many different units are used in thermochemistry. Report the units! Also report the sign when appropriate! 5.41 Consider the following reaction: 2 Mg (s) + O 2 (g) 2 MgO (s) ΔH = -1204 kJ (a) Is this reaction exothermic or endothermic?

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