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Chloride and Salinity - Lamont–Doherty Earth Observatory

9/8/11 8:15 AMChloride and SalinityPage 1 of 8 Chloride and SalinityINTRODUCTIONC hlorideChloride, in the form of the Cl ion, is one of the major inorganic anions, or negative ions, in saltwater andfreshwater. It originates from the dissociation of salts, such as sodium Chloride or calcium Chloride , inwater. NaCl(s) Na+(aq) + Cl (aq) CaCl2(s) Ca2+(aq) + 2 Cl (aq)These salts, and their resulting Chloride ions, originate from natural minerals, saltwater intrusion intoestuaries, and industrial of Chloride Ions River streambeds withsalt-containing minerals Runoff from salted roads Irrigation water returned to streams Mixing of seawater with freshwater Chlorinated drinking water Water softener regenerationThere are many possible sources of manmade salts that may contribute to elevated Chloride Chloride and calcium Chloride , used to salt roads, contribute to elevated Chloride levels in drinking water and sodium- Chloride water softeners often increase Chloride levels in wastewaterof a drinking water, the salty taste produced by Chloride depends upon the concentration of the Chloride containing 250 mg/L of Chloride may have a detectable salty taste if the Chloride came from sodiumchloride.

A Vernier Chloride Ion-Selective Electrode is used to measure the chloride ion concentration in the water (in mg/L) either on site or after returning to the lab. Salinity can be determined using the relationship, salinity (ppt) = 0.0018066 5 Cl– (mg/L). Method 2: Salinity Using a Conductivity Probe (Seawater or Brackish Water)

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  Selective, Electrode, Ion selective electrode

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