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Electrochemistry

ElectrochemistryChemical reactions at an electrode, galvanic and electrolytic cellsA Chem1 Reference TextStephen K. Lower Simon Fraser University1 Table of contents1:Chemistry and electricity .. 3 Electroneutrality .. 3 Potential differences at interfaces .. 52:Electrochemical cells .. 6 Transport of charge within the cell .. 7 Cell description conventions .. 8 Electrodes and electrode reactions .. 8 Standard half-cell potentials .. 9 Reference electrodes .. 113:Prediction and significance of cell potentials .. 12 Cell potentials and the electromotive series .. 13 Cell potentials and free energy .. 134:The Nernst equation .. 18 Concentration cells .. 23 Thermodynamics of galvanic cells .. 23 Analytical applications of the Nernst equation .. 23 Membrane potentials.

larger (and more polarizable) anions will loosely bond (chemi-sorb) to the metal, creating a negative inner layer which is compensated by an excess of cations in the outer layer. Electrochemistry is the study of reactions in which charged particles (ions or electrons) cross the interface between two

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