free chlorine presentation.ppt

1 Breakpoint you Really Have a Free chlorine residual ?ChloraminationNitrificationDisi nfection ByproductsBob Spon, chemistSpon Water Consulting2 Water Quality Problems in Distribution Systems 160 responses to AWWA survey indicates % of annual reported problems: 44% Taste & Odor 43% Color & Turbidity 5% High Heterotrophic Plate Count 5% DBP s, coliforms, corrosion, misc. 3% Loss of disinfection residual Do you have a free Cl2residual?3 What is a free residual ? chlorine in pure H2O = HOCl + OCl- HOCl = Hypochlorous Acid OCl-= Hypochlorite Ion Free chlorine residual = HOCl / OCl- Free available chlorine is very reactive total chlorine Free = Combined Minimum system chlorine residuals: IL EPA: free / mg/L total IA DNR: mg/L free / mg/L total FL DEP: mg/L free / mg/L totalFree Available chlorine Residuals(HOCl H++ OCl-) chlorine DosageChlorine ResidualBreakpoint Chlorination CurveBreakpoint

What is a free residual? Chlorine in ‘pure’ H 2O = HOCl + OCl-HOCl = Hypochlorous Acid OCl-= Hypochlorite Ion Free chlorine residual = HOCl / OCl-Free ‘available’ chlorine is very reactive Total Chlorine – Free = Combined Minimum system chlorine residuals: IL EPA: 0.2 free / 0.5 mg/L total IA DNR: 0.3 mg/L free / 1.5 mg/L total

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  Total, Chlorine, Residual, Residual chlorine, Total chlorine

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