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How to Determine Conjugation! - UCLA

How to Determine conjugation ! Definition: Special stability provided by electron delocalization in three or more adjacent, parallel, overlapping p orbitals. Let's break it down: Special stability=lower electron energy Electron delocalization= electron density is not fixed to one place, it is spread across multiple atoms Three= our magic number/minimum requirement for conjugation Adjacent overlapping p orbitals= p orbitals that are parallel and next to each other. This usually results from (but is not limited to) alternating single and double bonds, which result in partial pi bond behavior (if you're not comfortable with this idea, review resonance structures!) For example: If you see two double bonds separated by a single bond, their orbitals will interact and become conjugated!! o If the double bonds are separated by two sigma bonds, these atoms are not conjugated.

How to Determine Conjugation! Definition: Special stability provided by electron delocalization in three or more adjacent,

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