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INTERACTION OF ALIPHATIC AMINES WITH …

Clays and Clay Minerals, Vol. 33, No. 4, 301-311, 1985. INTERACTION OF ALIPHATIC AMINES with . montmorillonite TO enhance adsorption OF. ORGANIC POLLUTANTS. TIMOTHY A. WOLFE, l TURGUT DEMIREL, AND E. ROBERT BAUMANN. Department of Civil Engineering, Engineering Research Institute Iowa State University, Ames, Iowa 50011. Abstract--X-ray powder diffraction studies were performed with propyl-, dodecyl-, and dodecyldiam- monium bentonites saturated with aqueous mixtures of eleven organic pollutants at concentrations of to 100%. The alkylammonium salt treatment separated the montmorillonite unit layers, which increased the interlamellar volume and exposed the interlamellar surfaces for adsorption of the organic pollutants. Washing the salt-treated clays with distilled water removed excess, physically adsorbed al- kylammonium ions that could interfere with adsorption of the organic pollutants.

Clays and Clay Minerals, Vol. 33, No. 4, 301-311, 1985. INTERACTION OF ALIPHATIC AMINES WITH MONTMORILLONITE TO ENHANCE ADSORPTION OF

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