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Introduction to Chemical Engineering: Chemical Reaction ...

======================================== ================== Introduction to Chemical Engineering: Chemical Reaction EngineeringProf. Dr. Marco MazzottiETH Swiss Federal Institute of Technology ZurichSeparation Processes Laboratory (SPL)July 14, 2015 Contents1 Chemical Rate of Reaction and dependence on temperature .. Material balance .. Conversion .. Energy balance ..52 Three types of Batch .. Continuous stirred tank reactor (CSTR) .. Plug flow reactor(PFR) ..73 Material balances in Chemical Batch .. Continuous stirred tank reactor (CSTR) .. Plug flow reactor(PFR) .. 104 Design of ideal reactors for first-order CSTR .. PFR .. Comparison of CSTR and PFR .. 135 Dynamic behavior of CSTR during start-up146 Reversible Material balance for reversible Reaction .. equilibrium -limited reactions .. 167 Thermodynamics of Chemical equilibrium178 Energy balance of a The general energy balance.

1 Chemical reactions 1.1 Rate of reaction and dependence on temperature We will once again look at the formation of ammonia (NH 3) from nitrogen and hydrogen (see section Chemical equilibrium of the thermodynamics chapter). This reaction follows the equation: N 2 + 3H 2 2NH 3 (1) H0 = 92 kJ mol S0 = 192 J mol K

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