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Ionic Conductor Composites: Theory and Materials

Journal of Electroceramics 5:2, 111 125, 2000#2000 Kluwer Academic Publishers. Manufactured in The Conductor Composites: Theory and MaterialsP. KNAUTHL aboratoire de Physico-Chimie des Mate riaux, Universite de Provence, Centre de St Charles, Case 26, F-13331 Marseille Cedex 3, FranceSubmitted October 14, 1999; Revised November 18, 1999; Accepted November 18, main theoretical concepts on Ionic conduction at interfaces, especially the space charge layermodel, are summarized in the rst part of this review: ion trapping or redistribution leads to charge carrieraccumulation, depletion or inversion and, consequently, to conductivity changes in composite con rmations of the space charge layer model and the complementary percolation model arediscussed. Major developments of Ionic Conductor composite Materials over the last 25 years are presented in thesecond part, including lithium and other alkaline ion conductors, copper and silver ion conductors, di- and trivalentcation and anion conductors, glass and polymer composites.

Journal of Electroceramics 5:2, 111–125, 2000 # 2000 Kluwer Academic Publishers. Manufactured in The Netherlands. Ionic Conductor Composites: Theory and Materials

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