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ISE Beginners Guide - Nico2000

1. A Beginners Guide to Ion-Selective Electrode Measurements Chris C Rundle BSc, PhD. ( Nico2000 Ltd, London, UK. ). First Public Version 5 May 2000, Last Update: 31 Jan. 2011. Please Email with any comments or suggestions for improvement. CONTENTS. 1) FOREWORD, RATIONALE AND ACKNOWLEDGEMENTS P3. 2) INTRODUCTION TO ION SELECTIVE ELECTRODES P4. a) Applications. b) Advantages 3) BASIC THEORY OF ISE MEASUREMENTS. P5. a) The pH Electrode. b) Differences Between pH and Other Ion-Selective Electrodes. 4) TYPES OF ION SELECTIVE ELECTRODES P7. a) General Discussion. b) Crystal-Membrane Electrodes: Fluoride. c) Impregnated-PVC-Membrane Electrodes: Potassium. d) Care and Maintenance of ISEs. 5) REFERENCE ELECTRODES P9. a) The Silver / Silver Chloride Single Junction Reference Electrode.

5 5) They are invaluable for the continuous monitoring of changes in concentration: e.g. in potentiometric titrations or monitoring the uptake of nutrients, or the consumption of reagents.

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