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Lecture 3: Coupling Constants Chem 117 - Harvard …

Chem 117E. KwanLecture 3: Coupling ConstantsJanuary 31, ConstantsScope of LectureEugene E. Kwanenergy diagramsfor J couplingthe chemicalshiftHelpful References chemical Fermicontactmodelfirst- vs. second-order spectraHoye's methodwhat aretypicalcouplings?problemsolving1. Nuclear Magnetic Resonance Lambert, ; Mazzola, Prentice-Hall, 2004. (Chapter 3)2. The ABCs of FT-NMR Roberts, University Science Books, 2000. (Chapter 10)3. Spectrometric Identification of Organic Compounds (7th ed.) Silverstein, ; Webster, ; Kiemle, Wiley, 2005. (useful charts in the appendices of chapters 2-4)4. Organic Structural Spectroscopy Lambert, ; Shurvell, ; Lightner, ; Cooks, Prentice-Hall, Organic Structure Analysis Crews, P. Rodriguez, J.; Jaspars, M. Oxford University Press, thank Professor Mazzola (Maryland/FDA) and ProfessorReich (Wisconsin-Madison) for providing useful thank Professor Reynolds (Toronto) for useful Questionsenergy A - J/2 B - J/2 A + J/2 B + J/2 A BJJspectrum:(1) What are Coupling Constants ?

E. Kwan Lecture 3: Coupling Constants Chem 117 January 31, 2012. Coupling Constants Scope of Lecture Eugene E. Kwan energy diagrams for J coupling the chemical shift Helpful References

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