Transcription of Organi II Mechanisms - Organic chemistry
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Organi II Mechanisms - Organic chemistry
Organic II Mechanisms 1. Alkadienes a. HX addition to a conjugated diene: b. General Diels-alder cycloaddition reaction(Diene must be in cis configuration): 2. Aromatics a. Electrophilic aromatic substitution (halogenation): b. Electrophilic aromatic substitution (Nitration): c. Electrophilic aromatic substitution (Sulfonation): d. Electrophilic aromatic substitution (Alkylation): e. Electrophilic aromatic substitution (Acylation): f. Nucleophilic substitution reaction of aryl halides with EWG (Meisenheimer complex; ortho/para only): g.
3. Alcohols oa. 3 alcohol- acid catalyzed dehydration: b. 2o, 3o alcohol dehydration with POCl 3: c. 3o alcohol to alkyl halide using HX (X= Cl, Br, I): d. 1o, 2o alcohol to alkyl halide using SOCl
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