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Organic Chemistry I: Reactions and Overview - Tufts University

Organic Chemistry I: Reactions and Overview Andrew Rosen Editor: Raghav Malik January 13, 2013. Contents I Library of Synthetic Reactions 3. II Organic Trends and Essentials 4. 1 The Basics: Bonding and Molecular Structure 4. Resonance Stability .. 4. 2 Families of Carbon Compounds 4. Strength of London Dispersion Forces (Polarizability) .. 4. Degree of Unsaturation .. 4. 3 An Introduction to Organic Reactions and Their Mechanisms 4. Comparing Acid Strengths .. 4. 4 Nomenclature and Conformations of Alkanes and Cycloalkanes 5. Ring Flipping .. 5. 5 Stereochemistry 5. Naming Enantiomers via the -R and -S System .. 5. Stereochemistry Examples .. 6. 6 Ionic Reactions - Overview 6. General Nucleophilic Substitution Reactions .. 6. Carbocation Stability .. 6. Factors A ecting the Rates of SN 1 and SN 2 Reactions .. 6. Elimination Reactions .. 7. summary .. 7. 7 Alkenes and Alkynes I - Overview 8. The E-Z System .. 8. Relative Stabilities of Alkenes.

6.4 Elimination Reactions Higher temperatures increase the rates of elimination reactions A product with a more substituted double bond is more stable and thus more favorable If tert-butoxide is used, sterics must be considered to nd out which hydrogen it takes through the E2 reaction 6.5 Summary

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