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Organic Chemistry I: Reactions and Overview - Tufts University

Organic Chemistry I: Reactions and Overview Andrew Rosen Editor: Raghav Malik January 13, 2013. Contents I Library of Synthetic Reactions 3. II Organic Trends and Essentials 4. 1 The Basics: Bonding and Molecular Structure 4. Resonance Stability .. 4. 2 Families of Carbon Compounds 4. Strength of London Dispersion Forces (Polarizability) .. 4. Degree of Unsaturation .. 4. 3 An Introduction to Organic Reactions and Their Mechanisms 4. Comparing acid Strengths .. 4. 4 Nomenclature and Conformations of Alkanes and Cycloalkanes 5. Ring Flipping .. 5. 5 Stereochemistry 5. Naming Enantiomers via the -R and -S System .. 5. Stereochemistry Examples .. 6. 6 Ionic Reactions - Overview 6. General Nucleophilic Substitution Reactions .. 6. Carbocation Stability .. 6. Factors A ecting the Rates of SN 1 and SN 2 Reactions .. 6. Elimination Reactions .. 7. Summary .. 7. 7 Alkenes and Alkynes I - Overview 8.

7.4 Acid-Catalyzed Dehydration of Alcohols Rearrangements, also known as 1,2 shifts, can occur in primary and secondary alcohol dehydration The more favored product is dictated by the stability of the alkene being formed orF dehydration of secondary alcohols, the positive charge is shifted through a hydride shift or alkyl shift

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