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Predictive Models of Li-ion Battery Lifetime - NREL

nrel is a national laboratory of the Department of Energy, Office of Energy Efficiency and Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. Predictive Models of Li-ion Battery Lifetime Kandler Smith, Eric Wood, Shriram Santhanagopalan, Gi-Heon Kim, Ying Shi, Ahmad Pesaran National Renewable Energy Laboratory Golden, Colorado IEEE Conference on Reliability Science for Advanced Materials and Devices Colorado School of Mines Golden, Colorado September 7-9, 2014 nrel /PR-5400-62813 2 Key Messages Semi-empirical Battery Lifetime Models are generally suitable for system design & control oLong-term validation still needed oStandardization would benefit industry oCharacterization requires expensive cell aging experiments Physics Lifetime Models are needed to reduce test time as well as guide future cell design oOpen questions remain how best to model electrochemo-thermo-mechanical processes across length- and time-scales Liu et al.

• Li plating • Electrolyte decomposition • Gas generation . Particle scale • SEI μ-cracking Fracture, damage of transport paths • Phase evolution, Electrode scale • Electrode creep, delamination, • Separator pore closure • Pore clogging . Cell scale • 3D elec, thermal, mech. inhomogeneities • Tab effects • Stack/wind

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