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Priority Rules for Naming Chiral Centers - The R,S System

1. Prioritize the four atoms, or groups of atoms, attached to the chiral center based on the atomic number of the atom that is bonded directly to the chiral center. The higher the atomic number, the higher the priority.! Number the four atoms, or groups of atoms, such that “1” has the highest priority and “4” has the lowest priority. 2.

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