Transcription of Professor J. Stephen Clark
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Professor J. Stephen Clark
1 Heterocyclic ChemistryHeterocyclic ChemistryProfessor J. Stephen ClarkRoom C4-04 Email: 20122 Recommended Reading Heterocyclic Chemistry J. A. Joule, K. Mills and G. F. Smith Heterocyclic Chemistry(Oxford Primer Series) T. Gilchrist Aromatic Heterocyclic Chemistry D. T. Davies3 Course Summary Definition of terms and classification of heterocycles Functional group chemistry: imines, enamines, acetals, enols, and sulfur-containing groups Synthesis of pyridinesIntroductionIntermediates used for the construction of aromatic heterocycles Synthesis of aromatic heterocycles Examples of commonly used strategies for heterocycle synthesis Carbon heteroatom bond formation and choice of oxidation state Pyridines General properties, electronic structure Electrophilic substitution of pyridines Nucleophilic substitution of pyridines Metallation of pyridinesPyridine derivatives Structure and reactivity of oxy-pyridines, alkyl pyridines, pyridinium salts.
10 Functional Group Chemistry Enols and Enolates R1 O R1 OH keto form enol form E R2 R2 R1 O R2 H H B R1 O R2 R1 O R2 ... thioketones thiols thioethers OH O R H2N O NH2 H2N NH NH2 NH2 O R O O R1 R2 NH2 NH R O O ... Ring Construction Manipulation of Oxidation State Y X Y X X, Y = O, S, NR δ+ δ+ conjugate addition δ+
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