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Reaction Kinetics - vallance.chem.ox.ac.uk

1. Reaction Kinetics Dr Claire Vallance First year, Hilary term Suggested Reading Physical Chemistry, P. W. Atkins Reaction Kinetics , M. J. Pilling and P. W. Seakins Chemical Kinetics , K. J. Laidler Modern Liquid Phase Kinetics , B. G. Cox Course synopsis 1. Introduction 2. Rate of Reaction 3. Rate laws 4. The units of the rate constant 5. Integrated rate laws 6. Half lives 7. Determining the rate law from experimental data (i) Isolation method (ii) Differential methods (iii) Integral methods (iv) Half lives 8. Experimental techniques (i) Techniques for mixing the reactants and initiating Reaction (ii) Techniques for monitoring concentrations as a function of time (iii) Temperature control and measurement 9. Complex reactions 10. Consecutive reactions 11. Pre-equilibria 12. The steady state approximation 13. Unimolecular' reactions the Lindemann-Hinshelwood mechanism 14.

2 1. Introduction Chemical reaction kinetics deals with the rates of chemical processes. Any chemical process may be broken down into a sequence of one or more single-step processes known either as elementary processes, elementary reactions, or elementary steps.Elementary reactions …

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