Transcription of Reaction Mechanisms - IITPK
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Reaction Mechanisms - IITPK
158 Essential Notes on General Organic Chemistry ( ) The IITian s Prashikshan Kendra Pvt. Ltd. Topics Coverage :- Substitution Reactions Free Radical Reactions SN1 Mechanism SN2 Mechanism SN1 v/s SN2 Mechanisms E1 Mechanism E2 Mechanism E1 v/s E2 Mechanisms Substitution v/s elimination Reactions Aromatic Substitution Electrophilic Mechanism Aromatic Substitution Nucleophilic Mechanism Addition Nucleophilic Mechanism Addition Electrophilic Mechanism Addition Free Radical Mechanism RARE Mechanisms : (SNi, E1cb, SN', NGP, Benzyne, Ipso) Rearrangements Introduction : How exactly does an organic Reaction take place is the subject of study in this chapter of Reaction Mechanisms . Just as detectives investigate a crime after it has taken place and arrive at a reasonable prediction about how the crime may have occurred, similarly organic chemists predict by a number of laboratory techniques using sophisticated instrumentation how an organic Reaction may have taken place.
Elimination, rearrangement Elimination [12] TS of slow step • Factors to decide whether S N 1 or S N 2 : Any factors that affects the energy of activation of a given type of reaction will affect the rate and / or mechanism. These factors are useful to decide whether S N 1 or S N 2 occurs : 1. Electronic effect . 2. Steric effect . 3.
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