Sample Exercise 12.1 Calculating Packing Efficiency
most solids fall between the density of lithium (0.5 g/cm 3) and that of iridium (22.6 g/cm ), so this value is reasonable. Practice Exercise Estimate the length of the cubic unit cell edge and the density of CsCl (Figure 12.26) from the ionic radii of cesium, 1.81 Å, and chloride, 1.67 Å. Answer: a = 4.02 Å and ρ= 4.31 g/cm3
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Sample Exercise 14.1 Calculating an Average Rate of Reaction
www.centrallyon.orgSample Exercise 14.1 Calculating an Average Rate of Reaction Solution Analyze We are given the concentration of A at 20 s (0.54 M ) and at 40 s (0.30 M ) and asked to calculate the
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www.centrallyon.orgThe rate law is therefore zero order in B (that is, n = 0). Rate = k[A]2[B]0 = k[A]2 Rate = k[A]2 = (4.0 10 3 M 1 s 1)(0.050 M)2 = 1.0 10 5 M/s Because [B] is not part of the rate law, it is irrelevant to the rate if there is at least some B present to react with A. Sample Exercise 14.6 Determining a Rate Law from Initial Rate Data
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Sample Exercise 15.1 Writing Equilibrium-Constant Expressions
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