Transcription of Structural Theories of Glass Formation - Missouri …
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Cer103 NotesShelby chapter BrowGlass structure (1) Structural Theories of Glass FormationZachariasen's Random Network Theory- 1932 (see Shelby pp. 7-10) Before Zachariasen, Glass structures wereconsidered to be comprised of nanocrystals-~20 size- estimated from broadening ofdiffraction patterns: 'breadth'~ /(t cos ),where is the x-ray wavelength, t is theparticle size, the Bragg angle. Problems: Glass densities are too small( 10%) and no SAXS in diffraction patternBragg's Law describes the conditions for constructive interference, and so theangle of incident x-rays that will produce intense diffraction peaks. Otherdiffraction angles will lead to destructive interference. The angle is related to thewavelength of the incident x-rays ( ) and the lattice (crystallographer) noted similar mechanical properties (elasticmodulus, etc.) between glasses and crystals and so expected similar structuralenergies similar underlying atomistic building blocks (cation polyhedra).
Cer103 Notes Shelby Chapter 5 5-2 R.K. Brow Glass Structure (1) Glasses possess a Continuous Random Network Glasses and crystals have the same building blocks (cation polyhedra) arranged
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