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Surfactants – classification, features and applications

Surfactants classification, features and applicationsSurfactants classification, features and applicationsN. D. Denkovand S. TcholakovaDepartment of Chemical Engineering,Faculty of Chemistry, Sofia University, Sofia, BulgariaLecture at COST P21 Training School Physics of droplets: Basic and advanced topics Borovets, Bulgaria, 12 13 July, 20101. Classification of Particles as foam and emulsion Role of Surfactants for various foam and emulsion properties:(a) Thin film drainage and stability(b) Foam rheology(c) Foam drainage(d) Ostwald ripening4. Current Low molecular mass Surfactants 9 Nonionic 9 Ionic9 Amphoteric Polymeric surfactants9 Synthetic9 Natural Particles as surfactant species9 Spherical vs.

Steric stabilization by nonionic surfactants Nonionic surfactants. Role of surfactant micelles Solution rheology (shampoos, dish-washing gels) higher solution viscosity Structural forces in foam films: Control of micelle shape: mixtures (SLES+CAPB), counterions (Ca2+), temperature (for EO surfactants)

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