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Test3 ch17b Buffer-Titration-Equilibrium Practice Problems

1 General Chemistry II Jasperse Buffers/ titrations /Solubility. Extra Practice Problems General Types/Groups of Problems : Buffers General p1 Titration Graphs and Recognition p10 What Kind of Solution/pH at End? p2 Titration Calculations p11 Preparation and Recognition of Buffers p4 pH Estimations/Calculations after acid /base are added (including at Equivalence Point) p12 Buffer Calculations p5 Solubility Problems p14 Disrupted Buffers: After acid or Base are Added p7 Impact on Solubility When Common Ions are Present p16 Titration-Related Problems p9 Impact of pH on Solubility p17 Key Equations Given for Test: For weak acids alone in water: [H+] = KaxWA[] For weak bases alone in water: [OH-] = KbxWB[] pZ= -logZ General definition for p of anything pH + pOH = 14 [H+][HO-] = x 10-14 KaKb= x 10-14 for conjugate acid /base pair For Buffer: pH = pKa + log[base]/[ acid ] Henderson-Hasselbalch Equation S = S (products) S (reactants) G = G (products) G (reactants) G = H T S (T in Kelvin) BUFFERS 1.

a. = 1.8 a solution of formic acid and sodium formate, K a ×10–4 b. = 1.8 a solution of acetic acid and sodium acetate, K a ×10–5 c. = 3.5 a solution of hypochlorous acid and sodium hypochlorite, K a ×10–8 d. = 5.8 a solution of boric acid and sodium borate, K a ×10–10 e. All of these solutions would be equally good choices for ...

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