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Test3 ch17b Buffer-Titration-Equilibrium Practice Problems

1 General Chemistry II Jasperse Buffers/Titrations/Solubility. Extra Practice Problems General Types/Groups of Problems : Buffers General p1 Titration Graphs and Recognition p10 What Kind of Solution/pH at End? p2 Titration Calculations p11 Preparation and Recognition of Buffers p4 pH Estimations/Calculations after acid/base are added (including at Equivalence Point) p12 Buffer Calculations p5 Solubility Problems p14 Disrupted Buffers: After Acid or Base are Added p7 Impact on Solubility When Common Ions are Present p16 Titration-Related Problems p9 Impact of pH on Solubility p17 Key Equations Given for Test: For weak acids alone in water: [H+] = KaxWA[] For weak bases alone in water: [OH-] = KbxWB[] pZ= -logZ General definition for p of anything pH + pOH = 14 [H+][HO-] = x 10-14 KaKb= x 10-14 for conjugate acid/base pair For Buffer: pH = pKa + log[base]/[acid] Henderson-Hasselbalch Equation S = S (products) S (reactants) G = G (products) G (reactants) G = H T S (T in Kelvin) BUFFERS 1.

a. fluoride ion and hydrofluoric acid. b. bromide ion and hydrobromic acid. c. phosphate ion and hydrogen phosphate ion. d. carbonate ion and hydrogen carbonate ion. e. phosphoric acid and dihydrogen phosphate ion. 15. Which of the following can be mixed together in water to produce a buffer solution? a. HClO 4 and NaClO 4 d. H 3PO 4 and NaH ...

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