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Two chiral centres (diastereoisomers) - Massey …

1. Two chiral centres ( diastereoisomers ). Mirror O O. S R Two enantiomers N. OH HO. N differ by absolute configuration HN NH2 NH2 NH. A molecule with 1 stereogenic centre exists as 2 stereoisomers or enantiomers Enantiomers have identical physical properties in an achiral environment A molecule with 2 stereogenic centres can exist as 4 stereoisomers Enantiomers (mirror images) still have identical physical properties diastereoisomers (non-mirror images) have different properties O2N O2N. CO2Me CO2Me O O. diastereoisomers trans cis enantiomers epoxide enantiomers epoxide mp = 141 C mp = 98 C.

123.702 Organic Chemistry enantiomers cis epoxide mp = 98°C Two chiral centres (diastereoisomers) • A molecule with 1 stereogenic centre exists as …

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