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Visualizing the McCabe-Thiele Diagram

36 December 2009 CEPR eactions and SeparationsPaul M. MathiasFluor this spreadsheet-based visualization and interactive analysis of the McCabe-Thiele Diagram to understand the foundations of distillation the McCabe-Thiele DiagramMore than 80 years ago, McCabe and Thiele developed a creative graphical solution tech-nique based on Lewis s assumption of constant molal overfl ow (CMO) for the rational design of distilla-tion columns (1). The McCabe-Thiele Diagram enabled decades of effective design and operational analysis of distillation columns, and has been used to teach several generations of chemical engineers to design and trouble-shoot distillation and other cascaded processes.

Figure 1 is a schematic diagram of a distillation col-umn with a total condenser and a partial reboiler. The par-tial reboiler is an equilibrium stage, but the total condenser is not. The stages are counted from the top down, with stage 1 at the top of the column where the refl ux enters. (Note that if a partial condenser is used, it will have ...

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