4. Canonical ensemble
The angular momentum vector L should be regarded as having two components – in our classical picture we neglect the moment of inertia around the molecular axis. Thus we have two more degrees of freedom, and E =3N(k B T/2)+2N(k B T/2) = (5/2)Nk B T. The first term is the translational part and the second rotational. Thus C V =(5/2)Nk B ...
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