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4. Canonical ensemble

4. Canonical ensemble

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97 CHAPTER 4. CANONICAL ENSEMBLE Figure 4.1.: The Einstein model for C V as a function of T/T E where k B T E = ￿ω E. The upper line is the Dulong-Petit law, and the lower dotted line schematically depicts the deviation of the theory from experiment at very low T. applies as well. The reason is this: in the Einstein model each atom

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