Surface Energy Data for PVC: Poly(vinyl chloride), …

1 Surface Energy data for PVC: Poly(vinyl chloride ), CAS # 9002-86-2 Source(a)Mst. Type(b) data (c)Comments(d)Ellison, 1954(8)Critical ST c = 39 mJ/m2; 20oCVarious test liquids; unplasticized , 1968(131)Critical ST c = 39 mJ/m2; no temp citedTest liquids: water, glycerol, formamide, alcohols, and long-chain , 1969(111)Critical ST c = 30 mJ/m2; 20oCTest liquids not , 1970(94)Critical ST c = mJ/m2; 25oCEthylene glycol/2-ethoxyethanol mixes, based on advancingcontact , 1970(94)Critical ST c = 49 mJ/m2.

2 25oCEthylene glycol/2-ethoxyethanol mixes, based on retreatingcontact , 1970(94)Critical ST c = mJ/m2; 25oCPolyglycol blends, based on advancing contact , 1970(94)Critical ST c = 49 mJ/m2; 25oCPolyglycol blends, based on retreating contact , 1970(94)Critical ST c = 31 mJ/m2; 25oCFormamide/2-ethoxyethanol mixes, based on advancingcontact angles.(d)Dann, 1970(94)Critical ST c = >56 mJ/m2; 25oCFormamide/2-ethoxyethanol mixes, based on retreatingcontact angles.(d)Dann, 1970(94)Critical ST c = >56 mJ/m2; 25oCPer ASTM D-2578, using formamide/2-ethoxyethanol , 2005(62)Critical ST c = 39 mJ/m2; no temp citedTest liquids not known; unplasticized , 2005(62)Critical ST c = 33-38 mJ/m2; no temp citedTest liquids not known; plasticized , 1970(94)Contact angle WA = 83o; 25oCSessile drop method; Surface cleaned with detergent and rinsedwith distilled , 1971(29)Contact angle WY = 87o; 20oCUnplasticized , 1980(118)Contact angle WY = 85o.

3 No temp citedMeasured 60 secs. after application of water droplet; surfacecleaned with petroleum ether and rinsed with methanol. PVCcontained 20% dioctyl , 1983(189)Contact angle WR = ; no temp citedSpin cast on silanized coverslips. Fully hydrated sampleimmersed in water; interface with advancing, submergedoctane , 1992(112)Contact angle WY = 60o; no temp citedPVC with < plasticizer or stabilizer. Cleaned by sonifi-cation in a 70/30 ethanol/water solution and rinsed withdistilled , 1994(113)Contact angle WY = ; no temp citedContact angle measured after stabilizing for 15 , 2000(99)Contact angle WY = 80o; no temp citedMeasured by sessile drop , 2000(171)Contact angle WA = ; 20oCMeasured by Wilhelmy plate , 2000(217)Contact angle WY = ; no temp citedSurface cleaned with light methanol , 2003(139)Contact angle WY = 89o; 20oCMeasured by sessile drop method.

4 Roll-coated polymer topcoatapplied to carbon steel; Surface degreased with ethanol, cleanedwith detergent, and rinsed in distilled water. PVC containedlinear alkyl groups as , 2003(106)Contact angle WY = 94o; 20oCMeasured by sessile drop method. Roll-coated polymer topcoatapplied to carbon steel; Surface degreased with ethanol, cleanedwith detergent, and rinsed in distilled water. PVC containedphthalates as , 2005(254)Contact angle WA = 98o; no temp citedShafrin, 1963(201)Contact angle s = mJ/m2 ( sd = , sp = );Test liquids not temp citedDann, 1970(94)Contact angle sd = 39 mJ/m2; 25oCVarious test , 1971(29)Contact angle s = mJ/m2 ( sd = ; sp = ); 20oCTest liquids: water and diiodomethane, by geometric meanequation; unplasticized , 1971(29)Contact angle s = mJ/m2 ( sd = ; sp = ); 20oCTest liquids: water and diiodomethane, by harmonic meanequation.

5 Unplasticized , 1972(191)Contact angle s = mJ/m2 ( sd = , sp = );Various test liquids; original results split polar component intono temp citedhydrogen- and non-hydrogen bonding , 1979(45)Contact angle c = mJ/m2; 20oCTest liquids not known; calculated by the equation of Oss, 1989(22)Contact angle s = mJ/m2 ( sLW = , sAB = ,Test liquids: water, alpha-bromonaphthalene, diiodomethane, s+ = , s- = ); 20oCformamide, and glycerin; acid-base , 1994(113)Contact angle s = mJ/m2 ( sLW = , sAB = ,Test liquids: water, formamide, and diiodomethane; acid-base s+ = , s- = ); no temp citedanalysis, calculated per Good and Van Oss(86).

6 Contact anglesmeasured after stabilizing for 15 , 1994(113)Contact angle s = mJ/m2; no temp citedTest liquids: water, formamide, and diiodomethane; acid-baseanalysis calculated by arithmetic and geometric , 1995(218)Contact angle s+ = , s- = ; no temp citedTest liquids not known; acid-base , 1999(116)Contact angle s = 44 mJ/m2 ( sLW = 43, sAB = ,Test liquids: water, alpha-bromonaphthalene, diiodomethane, s+ = , s- = ); 20oCformamide, and glycerin; acid-base analysis, based on referencevalues for water of + = mJ/m2 and - = 19 , 1999(134)Contact angle s = mJ/m2 ( sLW = , sAB = ,Test liquids not known; acid-base analysis based on reference s+ = , s- = ); no temp citedvalues for water of + = mJ/m2 and - = , 2000(171)Contact angle s = mJ/m2 ( sLW = , sAB = ,Various test liquids; acid-base analysis, by Good-van Oss s+ = , s- = ); 20oCmethod.

7 Commercial sample, unknown plasticizer , 2000(217)Contact angle s = mJ/m2 ( sLW = , sAB = ,Test liquids: water, diiodomethane, formamide, glycerin, and s+ = , s- = ); no temp citedethylene glycol; acid-base analysis. Cleaned with , 2003(262)Contact angle s = 38 mJ/m2 ( sd = ; sp = );Test liquids not temp , 2003(139)Contact angle s = mJ/m2 ( sd = ; sp = );Test liquids: water, diiodomethane, and formamide, measured20oCby sessile drop method. Roll-coated polymer topcoat appliedto carbon steel; Surface degreased with ethanol, cleaned withdetergent, and rinsed in distilled water.

8 PVC contained linearalkyl groups as , 2003(139)Contact angle s = mJ/m2 ( sd = ; sp = );Test liquids: water, diiodomethane, and formamide, measured20oCby sessile drop method. Roll-coated polymer topcoat appliedto carbon steel; Surface degreased with ethanol, cleaned withdetergent, and rinsed in distilled water. PVC containedphthalates as , 1971(29)From polymer melt s = mJ/m2 ( sd = ; sp = ); 20oCDirect measurement of polymer melt extrapolated to 20oC;polarity calculated from interfacial tension with PE byharmonic , 1982(18)From polymer melt s = mJ/m2; 20oCDirect measurement of polymer melt extrapolated to , 1968(131)Calculated s = 36 mJ/m2; no temp citedCalculated from glass temperature of , 1968(182)Calculated s = 43 mJ/m2; 20oCCalculated from molecular , 1971(193)Calculated s = mJ/m2.

9 No temp citedCalculated from parachor and cohesive Krevelen, 1976(85)Calculated s = 42 mJ/m2; no temp citedCalculated from parachor , 1982(18)Calculated s = mJ/m2; 20oCCalculated from cohesive Energy density and , 2007(110)Unknown s = mJ/m2 ( sd = , sp = 2); 20oCNo details available. 2009 Diversified Enterprises