SAFETY DATA SHEET - National Ref

1 SAFETY data SHEET MAPP Pro Gas Version Revision Date: Page 1 of 7 SAFETY data SHEET MAPP PRO GAS SECTION 1: IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING Product Identifier Product name: MAPP PRO GAS REACH Registration Number: If REACH registration numbers do not appear the substance is either exempt from registration, does not meet the minimum volume threshold for registration or the registration has not yet come due. Relevant identified uses of the substance or mixture and uses advised against Use: Hand torch fuel. Soldering gas Advised Against: No identified use advised against.

2 Details of the supplier of the SAFETY data SHEET Company name: National Refrigerants Ltd. 4 Watling Close Sketchley Meadows Business Park Hinckley LE10 3EZ Tel: +44(0)1455 630790 Fax: +44(0) 1455 630791 Email: Emergency telephone number Emergency Tel: +44(0) 1865 407333 SECTION 2: HAZARDS IDENTIFICATION Classification of the substance of mixture Classification under CHIP: F+ Extremely Flammable Most important adverse effect: High risk of fire and danger of explosion when accumulated in low-lying areas or enclosed spaces. Danger of suffocation in low-lying areas and enclosed spaces.

3 Label elements Regulation (EC) No. 1272/2008 Signal Word: Danger Hazard Statements H220: Extremely Flammable gas H280: Contains gas under pressure; may explode if heated Precautionary Statements: Prevention P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking P260: Do not breathe dust/fume/gas/mist/vapour/spray. P271: Use only outdoors or in a well-ventilated area. Response P377: Leaking gas fire: Do not extinguish, unless leak can be stopped safely. P381: Eliminate all ignition sources if safe to do so. SAFETY data SHEET MAPP Pro Gas Version Revision Date: Page 2 of 7 P304: IF INHALED: Remove person to fresh air and keep comfortable for breathing.

4 P312: Call a POISON CENTER or doctor/physician if you feel unwell. Storage P403+P233: Store in a well ventilated place. Keep container tightly closed. P405: Store locked up. Disposal P501: Dispose of contents/container in accordance with local/regional/ National /international regulation. Directives 67/458/EEC or 1999/45/EC: Label elements under CHIP: F+ Extremely flammable. Risk phrases R12 SAFETY phrases S2, S3, S9, S16, S33, S29. For full text of R and S-Phrases see Section 16. Other hazards May displace oxygen and cause rapid suffocation. SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS Substances Hazardous Ingredients: Mixtures PROPENE (PROPYLENE) EINECS CAS CHIP Classification CLP Classification Percent 204-062-1 115-07-1 F+ Extremely Flammable H220, H280 75 100% SOBUTANE EINECS CAS CHIP Classification CLP Classification Percent 200-857-2 75-28-51 F+ Extremely Flammable H220, H280 10 25 % SECTION 4: FIRST AID MEASURES Description of first aid measures Skin contact: Take off all contaminated clothing immediately and wash with soap and water.

5 Get medical attention if irritation develops and persists. If frostbite occurs immerse area in luke warm water Do not use hot water. Get medical assistance. Eye contact: Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Call a physician Ingestion: This is not considered a potential route of exposure. Inhalation: Remove from exposure, lie down. Move to fresh air. Keep patient warm and at rest. Artificial respiration and/or oxygen may be necessary. Call a physician or poison control centre immediately.

6 4. 2. Most important symptoms and effects, both acute and delayed SAFETY data SHEET MAPP Pro Gas Version Revision Date: Page 3 of 7 Skin contact: No data available. Eye contact: No data available Ingestion: Not a route of exposure. Inhalation: No data available Delayed/immediate effects: Indication of any immediate medical attention and special treatment needed Immediate/special treatment: Exposure may aggravate pre-existing respiratory disorders. Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES Extinguishing media Extinguishing media: CO2, Dry chemical, Water spray, fog, or foam.

7 Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixture Special hazards arising from the mixture Can form explosive gas-air mixtures. Pressure build-up in cylinders/tanks may cause them to explode. Hazardous thermal decomposition products can be formed under certain fire conditions : carbon monoxide. Advice for fire-fighters Advice for fire-fighters: In the event of fire wear self-contained breathing apparatus. Cool endangered cylinders with water spray. SECTION 6: ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions: Promptly evacuate personnel to safe areas.

8 Eliminate all sources of ignition No action shall be taken involving personal risk or without suitable training. Keep unnecessary personnel away. Environmental precautions Environmental precautions: Should not be released into the environment. Prevent further leakage or spillage if safe to do so. Prevent from entering into soil, ditches, sewers, waterways and/or Methods and material for containment and cleaning up Clean-up procedures: Material evaporates. Eliminate all sources of ignition. Ventilate area well. Stop flow of gas or liquid if possible. Immediately contact emergency personnel.

9 Reference to other sections Reference to other sections: Refer to Section 7 of SDS. Refer to Section 8 of SDS. SECTION 7: HANDLING AND STORAGE Precautions for safe handling Handling requirements: Eliminate all sources of ignition. Avoid spark promoters. Electrically ground/bond container and equipment. Conditions for safe storage, including any incompatibilities Storage conditions: Store in accordance with local/regional/ National /international regulations. Secure cylinders in an upright position at all times, close all valves when not in use. Store in a cool dry, well- SAFETY data SHEET MAPP Pro Gas Version Revision Date: Page 4 of 7 ventilated place.

10 Keep container tightly closed and sealed until ready for use. Protect cylinders from damage. Suitable packaging: Store in original cylinder only. Specific end use(s) Specific end use(s) No data available. SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION Control parameters Hazardous ingredients: PROPYLENE (CAS 115-07-1) 8 hour TWA 15 min. STEL 500 ppm Exposure controls Engineering measures: Use process enclosed, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. The engineering controls also need to keep gas, vapour, or dust concentrations below any lower explosive limits.